Yes, and pull a good vacuum on the system before adding the exact amount specified. Any air or moisture in the system, possibly introduced though bad/diy charging/checking procedures will cause the system to not cool properly. Even with appropriate pressures showing on gauges, there may contaminates (air/water) in the system that can cause the system to operate poorly. Many times I have simply evacuated and recharged what I thought was a properly charged system and have it cool better afterward.
That's not to say you MIGHT get it right squirting some random amount of r134 with the diy can from the auto parts store. Just please don't use the stuff with leak stop in it - it can/will clog a pro AC machine the next time a machine is used on that car.
Have never seen this cause a reduction in cooling performance but - with home units the first thing the ac tech does is change the air filter - has the cabin air filter been changed recently?
I have seen corroded condensers (from northern/coastal states) cause A/C cooling problems, the fins rot away from salt indigestion and simply can't cool the refrigerant properly.
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